Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?

Claudia M.P.Kronenburg; Catelijne H.M.Amijs; Peter Wijkens; Johann T.B.H.Jastrzebski; Gerard van Koten

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Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?

机译：芳基氰基铜酸盐的氧化分解过程中意外生成的芳基氰化物。转让不可转让的团体？

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Oxidative decomposition of cyanocuprates of the type CuLi(CN)Ar (Ar = [C_6H_4(CH_2NMe_2)-2]~-, 1a) or type CuLi_2(CN)Ar_2 (1b) shows the unexpected formation of aryl-cyanides in up ot 30% yield.

机译：CuLi（CN）Ar类型（Ar = [C_6H_4（CH_2NMe_2）-2]〜-，1a）或CuLi_2（CN）Ar_2（1b）类型的氰酸盐的氧化分解表明，在30℃以上会意外生成芳基氰化物％让。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2002年第6期|共3页
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Claudia M.P.Kronenburg; Catelijne H.M.Amijs; Peter Wijkens; Johann T.B.H.Jastrzebski; Gerard van Koten;
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1. Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group? [J] . Claudia M.P.Kronenburg, Catelijne H.M.Amijs, Peter Wijkens, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2002,第6期

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7. Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group? [O] . Kronenburg, Claudia M.P, Amijs, Catelijne H.M, Wijkens, Peter, 2002

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Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?

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