4'-Functionalized 2,2':6',2'-terpyridines as building blocks for supramolecular chemistry and nanoscience

摘要

Different mono-and bis-terpyridines were synthesized utilizing nucleophilic substitution of 4'-chloro-2,2':6',2"-terpyridine.In the case of the ono-functionalized ligands,different functioal groups opposite to the metal binding site could be introduced;with the bis-functionalized ligands building blocks for metal-containing polymers with a tailored alkyl-chain length were accessible.As examples,a functionalize dterpyridien cadmium(II) complex as well as a fullerene derivative were prepared.