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首页> 外文期刊>Physical Review, A. Atomic, molecular, and optical physics >Photodissociation of Br-2 molecules in an intense femtosecond laser field
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Photodissociation of Br-2 molecules in an intense femtosecond laser field

机译:飞秒激光场中Br-2分子的光解离

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We experimentally demonstrate the photodissociation process of Br-2 molecules in the intense femtosecond laser field by a dc-sliced ion velocity map imaging technique. We show that four fragment ions Brn+ (n = 1-4) are observed, and their kinetic energy increases while their angular distribution decreases with the increase of the charge number. We prove that the low (or high) charged fragment ions result from the photodissociation of the low (or high) charged parent ions. We explain the changes of the kinetic energy and angular distribution in these fragment ions by considering the potential energy curves of these parent ions that involve both the interaction of the Coulomb repulsive energy and chemical bonding energy. We also explain the experimental observation that the measured kinetic energy release in the experiment is much smaller than the theoretical calculation by enhanced ionization at a critical distance.
机译:我们通过直流切片离子速度图成像技术实验性地证明了在强飞秒激光场中Br-2分子的光解离过程。我们显示观察到四个碎片离子Brn +(n = 1-4),其动能增加,而其角分布随电荷数的增加而减小。我们证明,低(或高)带电碎片离子是由低(或高)带电母离子的光解作用产生的。我们通过考虑这些母离子的势能曲线来解释这些碎片离子的动能和角分布的变化,这些势能曲线涉及库仑排斥能和化学键能的相互作用。我们还解释了实验观察结果,即通过在临界距离处增强电离,实验中测得的动能释放量远小于理论计算值。

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