Cellulose acetate polymer film modified microstructured polymer optical fiber towards a nitrite optical probe

摘要

A novel microstructured polymer optical fiber (MPOF) probe for nitrites (NO_(2)~(-)) detection was made by forming rhodamine 6G (Rh 6G)-doped cellulose acetate (CA) on the side wall of array holes in a MPOF. It was found that the MPOF probe only have a response to nitrites in a certain concentration of sulfuric acid solution. The calibration graph of fluorescence intensity versus nitrites concentration was linear in the range of 2.0 X 10~(-4) g/ml-5.0 X 10~(-3) g/ml. The method possesses ease of chemical modification, low cost design, and potential for direct integration with existing instrumentation, and has been applied to the determination of nitrites in real samples with satisfactory results.