Controllable preparation of nanoparticles by drops and plugs flow in a microchannel device

摘要

Well controlled two-liquid-phase flows in a T-junction microchannel device have been realized. The system of H2SO4 and BaCl2, respectively, in two phases to form BaSO4 nanoparticles was used as a probe to characterize the microscale two-phase flow and transport conditions of a system with interphase mass transfer and chemical reaction. Nanoparticles with narrow size and good dispersibility were produced through drops or plugs flow in the microdevice. As a novel work, the influence of mass transfer and chemical reaction on interfacial tension and flow patterns was discussed based on the experiments. At the same time, the effect of the two-phase flow patterns on the nanoparticle size was also discussed. It was found that the increase of the amount of mass transfer and chemical reaction could change the flow patterns from plugs flow to drops flow. The drop diameter or plug length could be changed in a wide range. Accordingly, a new parameter of mu(0)u(c)/gamma(0)/Q(d) was defined to distinguish the flow patterns. The prepared nanoparticles ranged in size from 10 to 40 nm. Apparently, the particle size decreased with the increase of the drop diameter or plug length. Reasons were discussed based on the mass transfer direction and speed in drops and plugs flow patterns.