Carbon nanotube growth from Langmuir-Blodgett deposited Fe _3O _4 nanocrystals

摘要

We investigate colloidal Fe_3O_4 nanocrystals as a catalyst system for carbon nanotube (CNT) growth that allows for decoupling the CNT growth step from the catalyst shaping and activation step. The system consists of 6.4nm Fe_3O_4 nanocrystals synthesized using a solution-based thermal decomposition reaction and, subsequently, transferred as hexagonally ordered Langmuir-Blodgett (LB) monolayers on TiN substrates. We demonstrate for the first time aligned CNT growth from LB deposited nanocrystals on a metallic underlayer. The hexagonally ordered monolayers of catalyst particles show promising stability up to the CNT growth temperature. In situ TEM heating experiments were performed to find this onset of particle deformation and showed stability of the nanoparticles up to 600°C. The particle coalescence at high temperatures was also evidenced by the increasing CNT diameter, from 9.5nm at 580°C to 16nm at 630°C. By choosing to work at temperatures below the onset particle coalescence temperature, equivalent CNT diameters were obtained under different catalyst activation and growth conditions. The high stability of the catalyst on the metallic underlayer enables us to study CNT growth kinetics independently of the catalyst shaping step. This work opens a route towards combining growth studies with an electrical evaluation of the CNT growth as the TiN can be used as the bottom contact.