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Insitu monitoring of flash-light sintering of copper nanoparticle ink for printed electronics

机译:原位监测印刷电子铜纳米粒子油墨的手电烧结

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In this work, a flash-light sintering process for Cu nanoinks was studied. In order to precisely monitor the milliseconds flash-light sintering process, a real-time Wheatstone bridge electrical circuit and a high-rate data acquisition system were used. The effects of several flash-light irradiation conditions (irradiation energy, pulse number, on-time, and off-time) and the effects of the amount of poly(N-vinylpyrrolidone) in the Cu nanoink on the flash-light sintering process were investigated. The microstructures of the sintered Cu films were analyzed by scanning electron microscopy. To investigate the oxidation or reduction of the oxide-covered copper nanoparticles, a crystal phase analysis using x-ray diffraction was performed. In addition, the sheet resistance of Cu film was measured using a four-point probe method. From this study, it was found that the flash-light sintered Cu nanoink films have a conductivity of 72Ωm/sq without any damage to the polyimide substrate. Similar nanoinks are expected to be widely used in printed and flexible electronics products in the near future.
机译:在这项工作中,研究了铜纳米油墨的闪光烧结工艺。为了精确监控毫秒级的闪光灯烧结过程,使用了实时惠斯通电桥电路和高速数据采集系统。 Cu纳米油墨中几种闪光照射条件(照射能量,脉冲数,开启时间和关闭时间)以及聚(N-乙烯基吡咯烷酮)含量对闪光烧结过程的影响为调查。通过扫描电子显微镜分析了烧结的Cu膜的微观结构。为了研究被氧化物覆盖的铜纳米颗粒的氧化或还原,进行了使用X射线衍射的晶相分析。另外,使用四点探针法测量Cu膜的薄层电阻。从该研究中发现,闪光烧结的Cu纳米墨水膜具有72Ωm/ sq的电导率,而不会损坏聚酰亚胺衬底。预计在不久的将来,类似的纳米墨水将广泛用于印刷和柔性电子产品中。

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