Anthracene Based Conjugated Polymers: Correlation between π-π-Stacking Ability, Photophysical Properties, Charge Carrier Mobility, and Photovoltaic Performance

摘要

This article reports on the synthesis, characterization and properties of a series of anthracene- containing poly(p-phenylene-ethynylene)-alt-poly(p-phenylene-vinylene)s (PPE-PPV) copolymers with general constitutional unit (Ph-CtC-Anthr-CtC-Ph-CHdCH-Ph-CHdCH-)n denoted AnE-PV. Solely linear (AnE-PVaa, -ad, -ae) and solely branched (AnE-PVbb) as well as mixed linear and branched (AnE-PVab, -ac, -ba, -cc) alkoxy side chains were grafted to the backbone in order to tune the π-π-stacking ability of the materials. It has been possible to establish a correlation between π-π-stacking ability, absorptive behavior, charge carrier mobility, solar cell active layer nanoscale morphology and resulting photovoltaic performance. Solar cells energy conversion efficiencies between 0.34% and 3.14% were achieved. The best performancewas achieved fromAnE-PVab showing both stacking ability and highest π-π-stacking distance of 0.386 nm as compared to 0.380 nm for the others. Poorer performance resulted from polymers with no inclination to stack, AnE-PVba, -bb, although they exhibited the higher charge carrier mobilities. Hole mobilities range from 1.5 10-5 cm2/V.s (AnE-PVad) to 4.5 10-4 cm2/V.s (AnE-PVba). An increase of the open circuit voltage from～650mVto～900mVis observedwith decreasing side chain density. In case of the AnE-PVcc:PCBM(1:1) blend a 2-fold increase in solar cell efficiency (from 1% to 2%) was obtained when the active layer was spin cast from a 1:1 mixture of chloroform:chlorobenzene instead of using chlorobenzene.