Microstructure and electrochemical properties of PrBaCo_2O_(5+δ)Ce_(0.9)Gd_(0.1)O_(1.95) vertically aligned nanocomposite thin film as interlayer for thin film solid oxide fuel cells

摘要

A thin layer of a vertically aligned nanocomposite (VAN) structure of PrBaCo_2O_(5+δ) (PBCO) and Ce_(0.9)Gd_(0.1)O_(1.95) (GDC) between the cathode and the electrolyte was demonstrated by a pulsed laser deposition (PLD) technique for thin film solid oxide fuel cells (TFSOFCs). The VAN structured PBCO/GDC thin film shows high quality epitaxial growth on single crystal SrTiO_3 substrate at high deposition temperatures. It also has a lattice matching relation between the PBCO and GDC vertical nanocolumns. The symmetric cells with the VAN interlayer are found to have a lower area specific resistance (ASR) of 2.1 Ω cm~2 compared to that of the ones without the interlayer (2.5 Ω cm~2) at 400℃. The maximum power density of the single cell prepared with the VAN interlayer was 151, 263, and 350mW cm~(-2), respectively, at 650, 700, and 750℃ with an open circuit voltage (OCV) of 0.88 V at 750 ℃. The PBCO/GDC VAN interlayer could perform as a transition layer that enhances adhesion and relieves stress from different thermal expansion coefficients (TECs) and lattice parameters between the cathode and the electrolyte in TFSOFCs.