_2Sb _(18)S _(29): A novel three-dimensional framework thioantimonate(III) templated by [Ni(phen) 3] complexes

Du K.-Z.; Feng M.-L.; Li L.-H.; Hu B.; Ma Z.-J.; Wang P.; Li J.-R.; Wang Y.-L.; Zou G.-D.; Huang X.-Y.

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >_2Sb _(18)S _(29): A novel three-dimensional framework thioantimonate(III) templated by [Ni(phen) 3] complexes

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_2Sb _(18)S _(29): A novel three-dimensional framework thioantimonate(III) templated by [Ni(phen) 3] complexes

机译：_2Sb _（18）S _（29）：一种由[Ni（phen）3]配合物模板化的新型三维构架硫代锑酸盐（III）

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A novel thioantimonate(III), namely, [Ni(phen) _3] _2Sb _(18)S _(29) (1; phen = 1,10-phenanthroline), has been solvothermally synthesized. Its structure features a three-dimensional framework with the largest channels in thioantimonates. The chiral [Ni(phen) _3] ~(2+) cations and the Sb:S ratio (1:1.611) in 1 are unique among those in the reported thioantimonates. The thermal stability, optical properties, and electric conductivity as well as the theoretical band structure and density of state of 1 have also been studied.

机译：溶剂热合成了一种新型的硫代锑酸盐（III），即[Ni（phen）_3] _2Sb _（18）S _（29）（1; phen = 1,10-菲咯啉）。它的结构具有一个三维框架，在硫代锑酸盐中具有最大的通道。在报告的硫代锑酸盐中，手性[Ni（phen）_3]〜（2+）阳离子和Sb：S比（1：1.611）在1中是唯一的。还研究了热稳定性，光学性质和电导率以及理论上的能带结构和1的状态密度。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2012年第7期|共3页
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Du K.-Z.; Feng M.-L.; Li L.-H.; Hu B.; Ma Z.-J.; Wang P.; Li J.-R.; Wang Y.-L.; Zou G.-D.; Huang X.-Y.;
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1. _2Sb _(18)S _(29): A novel three-dimensional framework thioantimonate(III) templated by [Ni(phen) 3] complexes [J] . Du K.-Z., Feng M.-L., Li L.-H., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第7期

机译：_2Sb _（18）S _（29）：一种由[Ni（phen）3]配合物模板化的新型三维构架硫代锑酸盐（III）
2. Solvothermal synthesis of two 2-d Thioantimonates(III) with metal complexes as template ions, [M(dap)(3)]Sb4S7 (M= Ni-2+ and Co-2+) [J] . Zhou M, Bian GQ, Zhang Y, Zeitschrift fur Anorganische und Allgemeine Chemie . 2007,第15期

机译：以金属配合物为模板离子[M（dap）（3）] Sb4S7（M = Ni-2 +和Co-2 +）溶剂热合成两种2-d硫代锑酸盐（III）
3. Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(III) complexes: [Ni(C3H10N2)(3)]Sb4S7, [C4H14N2]Sb8S13 center dot H2O, and [C6H18N2]Sb10S16 center dot H2O [J] . Zhang M, Sheng TL, Huang XH, European journal of inorganic chemistry . 2007,第11期

机译：溶剂热合成，晶体结构和三层硫代锑酸盐（III）配合物的热稳定性：[Ni（C3H10N2）（3）] Sb4S7，[C4H14N2] Sb8S13中心点H2O和[C6H18N2] Sb10S16中心点H2O
4. Hydrothermal Synthesis and Crystal Structure of a Novel Discrete Dodecanuclear62+ Iodocuprate(I) Cu10I16 - with Ni(phen)3 as a Template [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以Ni（phen）3为模板的新型离散十二碳六烯碘酸盐（I）Cu10I16-的水热合成和晶体结构
5. Organometallic photonucleases. I. DNA cleavage by the photolysis of cyclopentadienyl metal complexes: Mechanistic studies and sequence selectivity of strand scission by CpW(CO)3CH3. II. Footprinting of chromatin structure and chromatin remodeling by SWI/SNF utilizing CpW(CO)3CH3. III. Dual mechanisms of DNA damage by MoX(eta3-allyl)(CO)3(phen) complexes. [D] . Downs, Jennifer. 2005

机译：有机金属光核酸酶。 I.通过环戊二烯基金属配合物的光解来切割DNA：通过CpW（CO）3CH3进行断裂的机理研究和序列选择性。二。 SWI / SNF利用CpW（CO）3CH3进行染色质结构足迹测定和染色质重塑。三， MoX（eta3-烯丙基）（CO）3（phen）复合物对DNA的双重破坏机制。
6. Photochemistry of framework-supported M(diimine)(CO)3X complexes in three-dimensional lithium carboxylate metal–organic frameworks: monitoring the effect of framework cations [O] . Thomas J. Reade, Thomas S. Murphy, James A. Calladine, -1

机译：三维羧酸锂金属-有机骨架中骨架支撑的M（diimine）（CO）3X配合物的光化学：监测骨架阳离子的作用
7. Polyoxometalate-Supported Transition Metal Complexes and Their Charge Complementarity: Synthesis and Characterization of M(OH)6Mo6O18{Cu(Phen)(H2O)2}2M(OH) 6Mo6O18{Cu(Phen)(H2O) Cl}25H2O (M = Al3+, Cr3+) [O] . -1

机译：多氧酸盐负载的过渡金属配合物及其电荷互补：M（OH）6MO6O18 {Cu（H 2 O）2} 2 M（OH）6MO6O18 {Cu（Phen）（H2O）Cl} 2的合成及表征 5H2O（m = Al3 +，Cr3 +）
8. XAS studies of Ni(I), Ni(II), and Ni(III) complexes [R] . Furenlid, L. R. , Renner, M. W. , Fujita, E. 1995

机译：Xas研究Ni（I），Ni（II）和Ni（III）配合物

_2Sb _(18)S _(29): A novel three-dimensional framework thioantimonate(III) templated by [Ni(phen) 3] complexes

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