Synthesis of the hydroxide cluster [Al13(μ3-OH) 6(μ-OH)18(H2O)24]15+ from an aqueous solution

Wang W.; Wentz K.M.; Hayes S.E.; Johnson D.W.; Keszler D.A.

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Synthesis of the hydroxide cluster [Al13(μ3-OH) 6(μ-OH)18(H2O)24]15+ from an aqueous solution

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Synthesis of the hydroxide cluster [Al13(μ3-OH) 6(μ-OH)18(H2O)24]15+ from an aqueous solution

机译：由水溶液合成氢氧化物团簇[Al13（μ3-OH）6（μ-OH）18（H2O）24] 15+

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A scalable synthesis of the "flat" tridecameric inorganic cluster [Al13(μ3-OH)6(μ-OH)18(H 2O)24]15+ has been realized by treating an aqueous aluminum nitrate solution with a zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55% relative to the starting reagent Al(NO3)3. Products have been characterized by X-ray diffraction and solid-state 27Al MAS and MQMAS NMR.

机译：通过在室温下用锌金属粉末处理硝酸铝水溶液，已经实现了可扩展的“扁平”十三聚体无机簇[Al13（μ3-OH）6（μ-OH）18（H 2O）24] 15+的合成。室内温度。相对于起始试剂Al（NO3）3，单晶和多晶样品的产率容易超过55％。产品已通过X射线衍射和固态27Al MAS和MQMAS NMR进行了表征。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2011年第11期|共3页
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Wang W.; Wentz K.M.; Hayes S.E.; Johnson D.W.; Keszler D.A.;
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1. Synthesis of the hydroxide cluster [Al13(μ3-OH) 6(μ-OH)18(H2O)24]15+ from an aqueous solution [J] . Wang W., Wentz K.M., Hayes S.E., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第11期

机译：由水溶液合成氢氧化物团簇[Al13（μ3-OH）6（μ-OH）18（H2O）24] 15+
2. Solid-State ~(69)Ga and ~(71)Ga NMR Study of the Nanoscale Inorganic Cluster [Ga_(13)(μ3-OH)6(μ2-OH)_(18)(H2O)_(24)](NO3)_(15) [J] . Zayd L. Ma, Katherine M. Wentz, Blake A. Hammann Chemistry of Materials: A Publication of the American Chemistry Society . 2014,第17期

机译：纳米级无机簇[[Ga_（13）（μ3-OH）6（μ2-OH）_（18）（H2O）_（24）]的固态〜（69）Ga和〜（71）Ga NMR研究NO3）_（15）
3. Synthesis and structures of novel octadecanuclear clusters [Cu_(12)RE_6(μ_3-OH)_(24)(pyb)_(12)(H_2O)_(18)(μ_(12)-ClO_4)]~(17+)(RE =Sm, Eu) [J] . CHEN Xiaoming, WU Yuluan, WANG Ruji Science in China. Series B, Chemistry . 1996,第5期

机译：新型十八核簇[Cu_（12）RE_6（μ_3-OH）_（24）（pyb）_（12）（H_2O）_（18）（μ_（12）-ClO_4）]〜（17+）的合成与结构（RE = Sm，Eu）
4. Energetics of Al13 Keggin Cluster Compounds: Na(AlO4)A112(OH)24(MO4)4- 12H2O (M = S, Se) [C] . Christopher Armstrong North American Thermal Analysis Society conference . 2011

机译：Al13 Keggin簇化合物的能量学：Na（AlO4）A112（OH）24（MO4）4- 12H2O（M = S，Se）
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6. Crystal structure of Y6(μ6-O)(μ3-OH)8(H2O)24I8·8H2O [O] . François Le Natur, Guillaume Calvez, Olivier Guillou, 2014

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8. Volumetric properties of vapor saturated aqueous potassium hydroxide solutions from 0/sup 0/ to 400/sup 0/ and vapor saturated aqueous sodium hydroxide solutions from 0/sup 0/ to 350/sup 0/ based on a regression of the available literature data [R] . 1977

机译：蒸汽饱和氢氧化钾水溶液的体积性质从0 / sup 0 /至400 / sup 0 /和蒸汽饱和氢氧化钠水溶液0 / sup 0 /至350 / sup 0 /基于现有文献数据的回归

Synthesis of the hydroxide cluster [Al13(μ3-OH) 6(μ-OH)18(H2O)24]15+ from an aqueous solution

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