Structure Investigations of Dichloroaluminum Benzoates: An Unprecedented Example of a Monomeric Aluminum Complex with a Chelating Carboxylate Ligand

Florjanczyk Z; Bury W; Zygadlo-Monikowska E; Justyniak I; Balawender R; Lewinski J

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Structure Investigations of Dichloroaluminum Benzoates: An Unprecedented Example of a Monomeric Aluminum Complex with a Chelating Carboxylate Ligand

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Structure Investigations of Dichloroaluminum Benzoates: An Unprecedented Example of a Monomeric Aluminum Complex with a Chelating Carboxylate Ligand

机译：苯甲酸二氯铝的结构研究：具有螯合羧酸盐配体的单体铝配合物的前所未有的例子

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摘要

Dichloroaluminum benzoate and its adducts with Lewis bases show a large structural variety from molecular complexes to ionic species as indicated by X-ray diffraction, spectroscopic studies, and quantum-chemical calculations.

机译：X射线衍射，光谱研究和量子化学计算表明，苯甲酸二氯铝及其与Lewis碱的加合物显示出从分子络合物到离子物种的巨大结构变化。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2009年第23期|共3页
作者
Florjanczyk Z; Bury W; Zygadlo-Monikowska E; Justyniak I; Balawender R; Lewinski J;
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正文语种 eng
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MOLECULAR-STRUCTURE; ORGANOALUMINUM; ACIDS; ELECTROLYTES; ALUMOXANES; TETRANUCLEAR; ADDITIVES; BOEHMITE; ADDUCT;

机译：分子结构;有机铝;酸;电解质;铝氧烷;四核;添加剂;勃姆石;添加剂;

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1. Structure Investigations of Dichloroaluminum Benzoates: An Unprecedented Example of a Monomeric Aluminum Complex with a Chelating Carboxylate Ligand [J] . Florjanczyk Z, Bury W, Zygadlo-Monikowska E, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第23期

机译：苯甲酸二氯铝的结构研究：具有螯合羧酸盐配体的单体铝配合物的前所未有的例子
2. Hydrogen-Bonded Network and Layered Supramolecular Structures Assembled from C1O_4~ Counterions with Unprecedented Monomeric [AgL_2]~+and Chain Polymeric [AgL_2]_N~(N+) Complex Cations (L = Thioamide or Thiourea-Like Ligands) [J] . Alexandre Lopez, Robert A.Coxall, William Clegg, European journal of inorganic chemistry . 2004,第24期

机译：氢键网络和层状超分子结构，由C1O_4〜抗衡离子组成，具有前所未有的单体[AgL_2]〜+和链聚合的[AgL_2] _N〜（N +）复杂阳离子（L =硫代酰胺或硫脲样配体）
3. Tetranulclear manganese carboxylate clusters with imidazole-carboxylate chelating ligands.X-ray crystal structure of the 4-imidazoleacetate complex [J] . Colette Boskovic, Kirsten Folting, George Christou Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第18a19期

机译：四核锰羧酸盐簇与咪唑-羧酸盐螯合配体.4-咪唑乙酸盐配合物的X射线晶体结构
4. RUTHENIUM CATALYSTS BEARING O-CHELATING CARBOXYLATE LIGAND: POTENTIAL CHEMO-SWITCHABLE ROMP CATALYSTS [C] . RAFAL GAWIN, KAROL GRELA NATO Advanced Study Institute on New Smart Materials via Metal Mediated Macromolecular Engineering: from Complex to Nano Structures . 2009

机译：载体含有O-螯合羧酸盐配体的钌催化剂：潜在的化学可切换romp催化剂
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Synthesis crystal structure and investigation of mononuclear copper(II) and zinc(II) complexes of a new carboxylate rich tripodal ligand and their interaction with carbohydrates in alkaline aqueous solution [O] . Christopher D. Stewart, Mayra Pedraza, Hadi Arman, -1

机译：一种新的富含羧酸盐的三脚架配体的单核铜（II）和锌（II）配合物的合成晶体结构及其在碱性水溶液中与碳水化合物的相互作用的研究
7. Syntheses and Crystal Structures of Intramolecularly Stabilized Organo Aluminum, Gallium, and Indium Compounds Containing the C, P-Chelating o-Carboranylphosphino Ligand o-C2B10H10(CH2PMe2)-C, P- (CabC, P). X-ray Structure of Pentacoordinated Group 13 Metal Complexes (CabC, P)2MX (M = Ga, In; X = Cl) [O] . -1

机译：分子间稳定有机铝，镓和含有C，P螯合O-碳硼酰基膦酰亚膦腈O-C2B10H10（CH2PME2）-C，P - （CABC，P）的含镓和铟化合物的合成和晶体化合物。五边形组13金属配合物（CABC，P）2MX（M = GA，IN; X = CL）的X射线结构

Structure Investigations of Dichloroaluminum Benzoates: An Unprecedented Example of a Monomeric Aluminum Complex with a Chelating Carboxylate Ligand

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