首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d-5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet
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Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d-5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet

机译:一维3d-5d双金属系统中的分子间接触调谐磁性质:从超磁体到单链磁体。

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摘要

Assembling [W(CN)(6)(bpy)](-) and magnetic anisotropic Mn Schiff bases produced two Mn-III(3d)-W-V(5d) bimetallic chains. Modulation of the types and degrees of interchain pi-pi interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.
机译:组装[W(CN)(6)(bpy)](-)和磁性各向异性Mn Schiff碱可产生两条Mn-III(3d)-W-V(5d)双金属链。一维配位聚合物中链间pi-pi相互作用的类型和程度的调节导致磁行为从亚磁特性到单链磁特性的变化。

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