Predicting Bondons by Goldstone Mechanism with Chemical Topological Indices

摘要

The Goldstone symmetry breaking algorithm is applied on phi(2) and phi(4) chemical field contributions weighted, respectively, by the sphericity and extreme-sphericity topological indices to provide for stable chemical bonding in the high temperature regime, the typical mass for the bondon, and the associated quantum boson. The method is applied to a representative series of polycyclic aromatic hydrocarbons providing an aromaticity hierarchy comparable with the scale-based on the chemical hardness; present calculations on the bondonic mass place the physical existence of that bosonic-bondonic quantum particle in the range of a few GeV and 10(-22) s, as typical for negatively charged massive bosons. (c) 2014 Wiley Periodicals, Inc.