Microwave Solid Phase Synthesis and Crystal Structure of Copper(II) Complex with 2-Hydroxy-benzoic acid(amino-pyridin-2-yl-methylene)hydrazide

摘要

One mononuclear copper(II) complex [CuLCl]·2H2O has been synthesized by 2-hydroxy-benzoic acid(amino-pyridin-2-yl-methylene)-hydrazide (L) with CuCl2·2H2O in microwave radiation assistance. It crystallizes in the monoclinic system, space group C2/c, with the cell parameters a = 14.8571(13) A, b = 12.4560(11) A, c = 16.5409(16) A, α = γ = 90.00°, β = 95.5770(10)°, V = 3046.6(5) A~3 and Z = 8. The Cu atom is surrounded by one O atom and two N atoms from 2-hydroxy-benzoic acid(amino-pyridin-2-yl-methy lene)-hydrazide molecule and one Cl from CuCl2 to form a quadrilateral coordination environment.