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Preparation and Properties of Novel Semi-Aromatic Co-Polyamide 6T/6

机译:新型半芳族共聚酰胺6T / 6的制备与性能

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摘要

Semi-aromatic co-polyamides 6T/6 was synthesized via solution polymerization using terephthalic acid, 6-diaminohexane and caprolactam as raw materials. The structure of the obtained samples was characterized by fourier transform infrared spectroscopy. The influence of solid-phase reaction on the melting point and melt index of copolymer and the effect of oligomer content and intrinsic viscosity on the mechanical properties were also discussed. The results show that the intrinsic viscosity can be adjusted by the solid-phase polymerization proeess, while the latter has no significant effect on the melting points. The intrinsic viscosity of the copolymer and the content of the monomer have a significant impact on the mechanical properties of materials.
机译:以对苯二甲酸,6-二氨基己烷和己内酰胺为原料,通过溶液聚合反应合成了半芳香族共聚酰胺6T / 6。通过傅立叶变换红外光谱对获得的样品的结构进行表征。还讨论了固相反应对共聚物熔点和熔体指数的影响,以及低聚物含量和特性粘度对机械性能的影响。结果表明,固相聚合过程可以调节特性粘度,而固相聚合过程对熔点没有明显影响。共聚物的特性粘度和单体含量对材料的机械性能有重要影响。

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