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首页> 外文期刊>Analytical chemistry >Electromigration Current Rectification in a Cylindrical Nanopore Due to Asymmetric Concentration Polarization
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Electromigration Current Rectification in a Cylindrical Nanopore Due to Asymmetric Concentration Polarization

机译:由于不对称浓度极化而在圆柱形纳米孔中进行电迁移电流整流

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摘要

We present experimental measurements of electromigration current through a single cylindrical nanopore. A single cylindrical nanopore with 175 nm diameter was fabricated in silicon in series with two micropores with 2 and 100 (mu)m diameters. Thick electrical double layers (EDLs) ((kappa)a approx= 1) exhibit current rectification due to asymmetric concentration polarization while thinner EDLs show nearly symmetric conductance. After the electric field is turned off, electrical current is measured and observed due to redistribution of ions in the concentration polarization layer.
机译:我们目前通过单个圆柱形纳米孔的电迁移电流的实验测量。在硅中以两个直径分别为2和100μm的微孔串联制造一个直径为175 nm的圆柱状纳米孔。厚的双电层(EDLs)(κa大约= 1)由于不对称的浓度极化而表现出电流整流,而较薄的EDL则表现出几乎对称的电导率。关闭电场后,由于离子在浓差极化层中的重新分布,因此测量并观察到电流。

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