Synthesis,Characterization,and Chirality of Dimeric N-Confused Porphyrin-Zinc Complexes:Toward the Enantioselective Synthesis of Bis(porphyrinoid) Systems

摘要

Oligoporphyrins have attracted much attention as a result of their properties related to the interaction between the aromatic subunits,and may find potential application in molecular electronics,nonlinear optics,and catalysis.Directly linked porphyrin oligomers are of special interest as the interaction between chromophores in these systems is expected to be particularly strong and tunable.