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Quaternary Cu _2CdSnS _4 nanoparticles synthesized by a simple solvothermal method

机译:简单溶剂热法合成四元Cu _2CdSnS _4纳米粒子

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摘要

Quaternary Cu _2CdSnS _4 nanoparticles, which are useful for the photovoltaic applications, were successfully synthesized by using a simple solvothermal route. Slightly polydispersed nanoparticles were obtained at temperature of 180 °C, analyzed by transmission electron microscopy (TEM). The cernyite structured Cu _2CdSnS _4 nanoparticles were confirmed by X-ray diffraction (XRD). The morphology and the stoichiometric ratio of the nanoparticles were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX). The chemical states of the elements in the nanoparticles were analyzed by high-resolution X-ray photoelectron spectroscopy (XPS). The band gap of the as-synthesized Cu _2CdSnS _4 nanoparticles was determined by UV-Vis absorption spectra measurement.
机译:通过使用简单的溶剂热途径成功合成了可用于光伏应用的第四级Cu _2CdSnS _4纳米粒子。在180°C的温度下获得略微多分散的纳米颗粒,通过透射电子显微镜(TEM)分析。通过X射线衍射(XRD)证实了方铅矿结构的Cu _2CdSnS _4纳米颗粒。通过扫描电子显微镜(SEM)和能量色散X射线分析(EDX)表征了纳米颗粒的形貌和化学计量比。通过高分辨率X射线光电子能谱(XPS)分析了纳米颗粒中元素的化学状态。通过UV-Vis吸收光谱测量来确定合成的Cu _2CdSnS _4纳米粒子的带隙。

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