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首页> 外文期刊>Chemistry Letters >MxOy/SO42-/dealuminated zeolite beta (M=Ti,Fe) as novel catalysts for alkylation of isobutane with 1-butene
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MxOy/SO42-/dealuminated zeolite beta (M=Ti,Fe) as novel catalysts for alkylation of isobutane with 1-butene

机译:MxOy / SO42- /脱铝沸石β(M = Ti,Fe)作为异丁烷与1-丁烯烷基化的新型催化剂

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摘要

A new kind of MxOy/SO42-/H-form dealuminated beta (DH beta) catalysts prepared here were applied to alkylation of isobutane with 1-butene. The group of MxOy/SO42-/DH beta (M = Ti, Fe) catalysts has a lower rate of deactivation and higher selectivity of this alkylation than other group of H beta and DH beta. It is proposed that the strong acid sites corresponding to the active sites fbr this alkylation can be formed by the interaction among DH beta, MxOy, and SO42-. [References: 8]
机译:此处制备的一种新型的MxOy / SO42- / H形式的脱铝β(DHβ)催化剂用于异丁烷与1-丁烯的烷基化。 MxOy / SO42- / DHβ(M = Ti,Fe)催化剂组的失活速率较低,且该烷基化反应的选择性高于Hβ和DHβ其他组。有人提出,可以通过DHβ,MxOy和SO42-之间的相互作用形成与该烷基化反应的活性位相对应的强酸位。 [参考:8]

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