The effect of firing conditions on electrical conductivity and electrochemical properties of Sr0.8La0.2TiO3-Ce0.9Gd0.1O1.95 composite anodes for solid oxide fuel cells

摘要

The electrical conductivity of Sr0.8La0.2TiO3 (SLT) increased significantly through reducing calcination and sintering processes. The electrical conductivity of SLT sintered three times under a reducing atmosphere was 249 S cm(-1) at 800 degrees C in a H-2 atmosphere, which is 40 times higher than that of SLT sintered in air. The enhanced electrical conduction might be caused by the variation in valence state from Ti4+ to Ti3+. The single-cell performance of the Sr0.8La0.2TiO3-Ce0.9Gd0.1O1.95 (SLT-GDC) composite anode improved with increasing amount of GDC. The SG (HHH)15 anode exhibited the highest maximum power density of 25 mW cm(-2) at 800 degrees C for CH4 fuel. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.