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Influence of the nanoaerosol fraction of industrial coal dust on the combustion of methane-air mixtures

机译:工业煤粉中的纳米气溶胶分数对甲烷-空气混合物燃烧的影响

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The mechanism of formation of nanosized aerosol particles during mechanical grinding of coal from Kuzbass mines is studied. The concentration and size spectrum of aerosol particles in a mine tunnel during cutter operation were measured using an aerosol spectrometer. It is found that 90% of the particles are less than 200 nm in size. In the nanometer range, there are two peaks corresponding to average diameters of 20 and 150 nm, the first of which is due to single particles, and the second to aggregates consisting of single particles. The formation of aerosol during mechanical coal grinding in a continuous flow mill was studied. The spectrum and morphology of the particles produced in the laboratory mill are in qualitative agreement with those for the nanoaerosol formed in the mine. The influence of the coal aerosol on the combustion of gas mixtures was studied. Laboratory experiments showed that the presence of the nanoaerosol in a lean methane-air mixture significantly increased its explosibility. This was manifested in an increase in the maximum pressure and a significant increase in the pressure rise rate during explosion. The study leads to the conclusion that the nanoaerosol is formed from the organic coal components released into the gas phase during local heating of coal on the cutter teeth.
机译:研究了库兹巴斯矿山煤炭机械研磨过程中形成纳米级气溶胶颗粒的机理。使用气溶胶光谱仪测量在切割机操作期间矿井隧道中气溶胶颗粒的浓度和粒径谱。发现90%的颗粒的尺寸小于200nm。在纳米范围内,有两个峰对应于20和150 nm的平均直径,第一个峰是由于单个颗粒,第二个峰是由单个颗粒组成的聚集体。研究了连续流磨机机械磨煤过程中气溶胶的形成。在实验室工厂生产的颗粒的光谱和形态与矿山中形成的纳米气溶胶的光谱和形态在质量上是一致的。研究了煤气溶胶对混合气燃烧的影响。实验室实验表明,稀薄的甲烷-空气混合物中存在纳米气溶胶会大大增加其爆炸性。这表现为爆炸期间最大压力的增加和压力上升率的显着增加。研究得出的结论是,纳米气溶胶是由煤在切齿上局部加热时释放到气相中的有机煤成分形成的。

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