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Biodiesel from Rubber Seed Oil on Heterogeneous Catalyst: An Effective Way to Use Byproducts from Rubber Processing

机译:非均相催化剂上橡胶籽油中的生物柴油:利用橡胶加工副产物的有效方法

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摘要

Rubber seed oil is a low valued byproduct from rubber processing in VietNam. By using it for high yielded biodiesel conversion, we value up not only this byproduct but also have an alternative feedstock supply for biodiesel production. This work studies the production of biodiesel from rubber seed oil by a solid alkaline catalyst Na_2SiO_3/SiO_2, which has an affordable cost and could reduce the disadvantages of the conventional homogenous catalysts. The optimal conditions for biodiesel production over as-synthesized Na_2SiO_3/SiO_2 are: calcining temperature of catalyst is 900℃, catalyst amount is 3% by weight, methanol to oil ratio 0. 3 v/v, temperature reaction = 60℃, time reaction = 5 hours and the conversion efficiency of biodiesel is 94.1%. Suggested maximum blending ratio of biodiesel - petroleum diesel is B 20 when the concentration of exhaust gases such as CO_x, NO_x, RH reduces significantly without engine modification.
机译:橡胶籽油是越南橡胶加工中的低价值副产品。通过将其用于高产生物柴油转化,我们不仅珍惜这种副产品,而且还为生物柴油生产提供了替代性的原料供应。这项工作研究了用固体碱性催化剂Na_2SiO_3 / SiO_2从橡胶籽油生产生物柴油,该催化剂具有可承受的成本,并且可以减少常规均相催化剂的缺点。合成后的Na_2SiO_3 / SiO_2上生物柴油生产的最佳条件为:催化剂的煅烧温度为900℃,催化剂的用量为3%(重量),甲醇与油的比为0。3v / v,温度反应= 60℃,时间反应= 5小时,生物柴油的转化效率为94.1%。当废气浓度(如CO_x,NO_x,RH)显着降低而无需改装发动机时,建议的生物柴油-石油柴油的最大混合比为B 20。

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