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Pressure Calibration at High Temperature in Flat-Belt type High Pressure Apparatus

机译:平带式高压设备的高温压力校准

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Pressure and temperature calibration of FB-belt type apparatus was carried out at pressures between 4 and 6 GPa and temperatures between 1000 and 1500 deg C using pressure and t4emperature condition of diamond formation and CaGeO_3 phase transition. Pressure and temperature points used as standard were minmum condition of diamond formation in the Ni-C system at 5.4 GPa and 1384 deg C and in the Fe-66Ni34-C system at 4.98 GPa and 1216 deg C. the temperature dependence of garnet-perovskite phase transition curve of CaGeO_3, P(GPa) =6.9-0.0008T (deg C), determined by Susaki et al. was also used as standard of the calibration. With increasing temperature the cell pressure increases about 20 percent between 1000 and 1500 deg C due to thermal expansion of NaCl used as pressure transmitting medium and the reaction cell. The amounts of pressure increase estimated both from the diamond formation and from CaGeO_3 phase transition agreed within 0.05 GPa.
机译:使用金刚石形成的压力和温度条件以及CaGeO_3相变,在4至6 GPa的压力和1000至1500摄氏度的温度下对FB带式设备进行压力和温度校准。用作标准的压力和温度点是在5.4 GPa和1384摄氏度的Ni-C系统中以及在4.98 GPa和1216摄氏度的Fe-66Ni34-C系统中金刚石形成的最低条件。石榴石-钙钛矿的温度依赖性由Susaki等人确定的CaGeO_3的相变曲线,P(GPa)= 6.9-0.0008T(摄氏度)。也用作校准的标准。随着温度的升高,由于用作压力传递介质和反应池的氯化钠的热膨胀,池压在1000至1500摄氏度之间增加了约20%。根据金刚石形成和CaGeO_3相变估算的压力增加量均在0.05 GPa之内。

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