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Pressure Calibration at High Temperature in Flat-Belt type High Pressure Apparatus

机译:平带型高压装置高温压力校准

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Pressure and temperature calibration of FB-belt type apparatus was carried out at pressures between 4 and 6 GPa and temperatures between 1000 and 1500 deg C using pressure and t4emperature condition of diamond formation and CaGeO_3 phase transition. Pressure and temperature points used as standard were minmum condition of diamond formation in the Ni-C system at 5.4 GPa and 1384 deg C and in the Fe-66Ni34-C system at 4.98 GPa and 1216 deg C. the temperature dependence of garnet-perovskite phase transition curve of CaGeO_3, P(GPa) =6.9-0.0008T (deg C), determined by Susaki et al. was also used as standard of the calibration. With increasing temperature the cell pressure increases about 20 percent between 1000 and 1500 deg C due to thermal expansion of NaCl used as pressure transmitting medium and the reaction cell. The amounts of pressure increase estimated both from the diamond formation and from CaGeO_3 phase transition agreed within 0.05 GPa.
机译:FB带式设备的压力和温度校准在4至6GPa的压力下,使用金刚石形成的压力和T4微观条件和CACEO_3相变的温度和1000和1500℃之间的温度。 用作标准的压力和温度点是在4.98GPa和1384℃和4.98GPa和1216℃的Fe-66Ni34-C系统中的Ni-C系统中金刚石形成的小型条件.Garnet-Perovskite的温度依赖性 CACEO_3,P(GPA)= 6.9-0.0008T(DEG C)的相转移曲线,由Susaki等人确定。 也被用作校准标准。 随着温度的升高,由于使用作为压力传递介质和反应细胞,电池压力由于NaCl的热膨胀而增加了1000至1500℃之间的约20%。 从金刚石形成和来自CACEO_3相转变估计的压力增加的量估计在0.05GPa内。

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