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Electrochemical Impedance Spectroscopy Analysis on the Effect of Steel Fiber Addition on Corrosion of Steel Bars in Mortar

机译:钢纤维添加对砂浆中钢筋腐蚀影响的电化学阻抗谱分析

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The question of how adding steel fiber (SF) to concrete would affect the corrosion behavior of steel reinforcing bars was studied by immersion tests in a 3 mass percent NaCl solution for 363 days. The tests were conducted on steel bar/mortar specimens with different SF content (0-2 vol percent). Each specimen's corrosion potential and electrochemical impedance were measured during the testing. Corrosion potential was not much affected by changes in the SF content. Electrochemical impedance measured at corrosion potentials was analyzed to get the charge-transfer resistance (R_(ct)) using an equivalent electrical circuit with the R_(ct), Warburg impedance, and a constant-phase element. The corrosion rate of steel bars in mortar estimated from the reciprocal of the R_(ct) decreased inversely to the SF content of the mortar, and correlated well with the rust area of the steel bars measure after the immersion tests. This shows that electrochemical impedance measurement is a useful method for diagnosing corrosion of steel in concrete. The inhibition of corrosion of the steel bars resulting from the SF addition was attributed to the consumption of dissolved oxygen by the corrosion of SF in the mortar.
机译:通过在3质量%NaCl溶液中浸泡测试363天,研究了在混凝土中添加钢纤维(SF)如何影响钢筋的腐蚀行为的问题。在具有不同SF含量(0-2%体积百分比)的钢筋/砂浆样品上进行了测试。在测试过程中测量了每个样品的腐蚀电位和电化学阻抗。 SF含量的变化对腐蚀潜能的影响不大。使用具有R_(ct),Warburg阻抗和恒定相元件的等效电路,分析在腐蚀电位下测得的电化学阻抗,以获得电荷转移电阻(R_(ct))。根据R_(ct)的倒数估算的砂浆中的钢筋腐蚀速率与砂浆中的SF含量成反比,并且与浸入试验后测得的钢筋锈蚀面积具有良好的相关性。这表明电化学阻抗测量是诊断混凝土中钢腐蚀的有用方法。 SF添加对钢筋的腐蚀抑制作用归因于砂浆中SF的腐蚀消耗了溶解的氧气。

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