Reactions of cyclomanganated complexes with carbon disulfide: routes to eta(2)-aryldithiocarboxylate-Mn(CO)(4) complexes and to the trithiocarbonate complex (mu(3)-CS3)(2)Mn-4(CO)(16)

摘要

Reaction of cyclomanganated aryl ketones with CS2 proceeds with insertion into the Mn-C bond to give eta(2)-dithiocarboxylato-Mn(CO)(4) compounds. With other cyclomanganated substrates such as that from Ph3P=S and also with Mn-2(CO)(10), CS2 gives (mu(3)-CS3)(2)Mn-4(CO)(16) with bridging trithiocarbonate ligands. (C) 2002 Elsevier Science B.V. All rights reserved. [References: 44]