Post-heat Treatment Effects on Cold-Sprayed Aluminum Coatings on AZ91D Magnesium Substrates

摘要

Commercially pure aluminum (CP-Al) powder was deposited by the cold spray process onto AZ91D magnesium (Mg) substrates that had been subjected to three different heat-treatment conditions: namely, as-cast (F), homogenized (T4), and artificially aged (T6). The substrate hardness was measured to be 80.7 ± 1.8, 73.7 ± 4.0, and 103.6 ± 7.4 HV_(0.025) for the F-, T4-, and T6-Mg alloy substrates respectively. Thick (～400 μm) and dense (below 1% porosity) Al coatings have been obtained. After post-deposition heat treatment at 400℃, the intermetallic Mg_(17)Al_(12) (β) and Al_3Mg_2 (γ) phases with different thicknesses were found to have formed at the coating/substrate interface depending on the holding time. While no significant thickness differences of the intermetallic layers were detected in the cases of F- and T6-AZ91D substrates, thicker layers formed on the T4-AZ91D substrate. It is believed that the higher Al concentration in the T4-AZ91D solid solution within the α-Mg could diffuse and contribute more easily to the growth of the intermetallic phases. The hardness of the β- and γ-phase was measured to be 260.5 ± 10.7 HV_(0.025) and 279.6 ± 13.7 HV_(0.025), respectively. Shear strength test results revealed lower adhesion strength after heat treatment, which is attributed to the presence of brittle intermetallic layers at the coating/substrate interface.