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首页> 外文期刊>Journal of thermal analysis and calorimetry >Influence of temperature on ultrasonic velocity measurements of ethanol+water+1-propanol mixtures
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Influence of temperature on ultrasonic velocity measurements of ethanol+water+1-propanol mixtures

机译:温度对乙醇+水+ 1-丙醇混合物超声速度测量的影响

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摘要

The ultrasonic velocity of the ternary mixtures ethanol+water+1-propanol at the range 288.15-323.15 K and atmospheric pressure, has been measured over the whole concentration range. The corresponding change of isentropic compressibility was computed from the experimental data. The results were fitted by means of a temperature dependent equation, such parameters being gathered. The obtained experimental values indicate varying extent of interstitial accommodation among unlike molecules as a function of steric hindrance attending to 1-propanol composition as key component and as a function of hydrogen bond and temperature attending to ethanol composition as key component.
机译:在整个浓度范围内,测量了三元混合物乙醇+水+ 1-丙醇在288.15-323.15 K范围内的超声速度和大气压。从实验数据计算出等熵压缩率的相应变化。通过依赖温度的方程拟合结果,收集这些参数。所获得的实验值表明,不同分子之间的间隙调节程度随作为1-丙醇组成的关键位点的空间位阻以及作为乙醇关键组成的氢键和温度的函数而变化。

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