Sewage sludge ash as an alternative low-cost oxygen carrier for chemical looping combustion

摘要

In this paper, novel low-cost oxygen carriers containing Fe_2O_3 are evaluated for use in chemical looping combustion. Sewage sludge ashes and reference samples were prepared and used in cyclic reduction and oxidation experiments in a thermogravimetric analyzer (TG). A gaseous (3 % H_2) fuel and a solid fuel (hard coal) were tested. Three-cycle CLC tests were carried out in the 600–800 ℃ temperature range and long-term testing was performed at 950 ℃. A reactivity study showed that the natural sewage sludge ash sample was stable during the cycling TG tests when hydrogen was used as a fuel at all of the temperatures investigated. Strong temperature effects on the oxygen transport capacity were observed. An onecycle test at 900 ℃ showed also that the sewage sludge ash successfully reacted with coal. The oxygen released was fully used for coal combustion, with appreciable reaction rate at temperature of ~750–800 ℃, that is significantly lower than that obtained for pure Fe_2O_3-based oxygen carrier. The oxidation reaction was much faster than the reduction reaction. Moreover, the sewage sludge ash showed a low tendency toward agglomeration in the cyclic test, which was superior to the behavior of synthetic materials. The sewage sludge ash exhibited also high mechanical strength, an attrition index of 1 % and a hightemperature resistance of 1,170 ℃ in a reducing atmosphere. We conclude that sewage sludge ash can be effectively used as a low-cost, valuable oxygen carrier in practical application in chemical looping combustion technology for power generation.