Crystallization and thermodynamic properties of titanium stannides

摘要

Thermodynamic properties of pure titanium stannides obtained by crucible-less growth techniques under vacuum are determined by differential scanning calorimetry and Knudsen effusion. The enthalpy, specific heat capacity, entropy and Gibbs energy temperature dependence were simulated using Maier and Kelly equations. Standard enthalpies of evaporation, formation and atomization of titanium stannides were determined and compared with earlier-known data.