Galvanic corrosion behavior of die cast AZ91D magnesium alloy in chloride solution

摘要

The galvanic corrosion behavior of die cast AZ91D magnesium alloy coupled with H62 brass, 316L stainless steel, A3 steel and LY12 aluminum alloy of different areas in 3.5 percent NaCl solution was studied. The free corrosion potentials, galvanic potentials and currents of these galvanic couples were measured. The galvanic effects were determined by the mass loss and regression method using three points. The results show that: (1) In these four kinds of couples AZ91D acts as the anode, whose galvanic corrosion behavior is mainly controlled by the cathodic polarization; (2) The free corrosion potentials of these four kinds of couples change a little with time and cathodic/anodic area ratio (CAAR); (3) The galvanic potential of AZ91D/LY12 moves positively with the increase of time and CAAR; (4) The galvanic currents increase with CAAR, but there is difference in the current change between different couples; (5) The anodic dissolution rate of the magnesium alloy increases by 2-3 orders after being coupled with these four kinds of metals and the galvanic effects of these couples have such a relation as gamma_(H62) > gamma_(316L S.S) > gamma_(LY12) > gamma_(A3).