A novel preparation of 3,3-dimethylbutyraldehyde via isomerization of 3,3-dimethyl-1-butene epoxide

Alan R.Katritzky; Yunfeng Fang; Indra Prakash

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A novel preparation of 3,3-dimethylbutyraldehyde via isomerization of 3,3-dimethyl-1-butene epoxide

机译：通过3,3-二甲基-1-丁烯环氧化物异构化制备3,3-二甲基丁醛的新方法

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摘要

3,3-Dimethylbutyraldehyde is prepared ina highly economical manner by regioselective isomerization of the title epoxide in the presence of LiTMP.

机译：在LiTMP存在下，通过标题环氧化物的区域选择性异构化，以非常经济的方式制备3,3-二甲基丁醛。

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《Journal of the Indian Chemical Society》 |2000年第12期|共2页
作者
Alan R.Katritzky; Yunfeng Fang; Indra Prakash;
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1. A novel preparation of 3,3-dimethylbutyraldehyde via isomerization of 3,3-dimethyl-1-butene epoxide [J] . Alan R.Katritzky, Yunfeng Fang, Indra Prakash Journal of the Indian Chemical Society . 2000,第11a12期

机译：通过3,3-二甲基-1-丁烯环氧化物异构化制备3,3-二甲基丁醛的新方法
2. Mechanistic Studies of Choline Oxidase with Betaine Aldehyde and Its Isosteric Analogue 3,3 -Dimethylbutyraldehyde [J] . Fan Fan, Markus W.Germann, Giovanni Gadda Biochemistry . 2006,第6期

机译：甜菜碱醛胆碱氧化酶及其等规类似物3,3-二甲基丁醛的机理研究
3. A convenient synthesis of 3,3-dimethylbutyraldehyde [J] . Zhi Guo, Rachel Sawyer, Indra Prakash Synthetic Communications . 2001,第21期

机译：3,3-二甲基丁醛的便捷合成
4. Pulsed MOCVD of Cu Seed Layer using a (Hfac)Cu(3,3-Dimethyl-1-Butene) Source Plus H_2 Reactant [C] . Jaebum Park, Heejung Yang, Jaegab Lee Symposium Proceedings vol.812; Symposium on Materials, Technology and Reliability for Advanced Interconnects and Low-k Dielectrics - 2004; 20040413-15; San Francisco,CA(US) . 2004

机译：使用（Hfac）Cu（3,3-二甲基-1-丁烯）源加H_2反应物对铜籽晶层进行脉冲MOCVD
5. Palladium-catalyzed isomerization of epoxides to carbonyl compounds: Scope and mechanism. [D] . Kulasegaram, Sanjitha. 1997

机译：钯催化环氧化物异构化为羰基化合物：范围和机理。
6. Soluble epoxide hydrolase contamination of specific catalase preparations inhibits epoxyeicosatrienoic acid vasodilation of rat renal arterioles [O] . Kathryn M. Gauthier, Lauren Olson, Adam Harder, -1

机译：特定过氧化氢酶制剂的可溶性环氧化物水解酶污染抑制大鼠肾小动脉的环氧二十碳三烯酸血管舒张
7. Preparation, Stereochemistry, and Kinetics of Isomerization and Racemization of Acetylacetonato Complexes of Chromium(III) Containing 2,2′-BipyridineN,N′-Dioxide or Its 3,3′-Dimethyl Derivative [O] . Hideaki Kanno, Shunji Utsuno, Junnosuke Fujita 1984

机译：含有2,2'-双吡啶，N'-二氧化氮的铬（III）乙酰丙酮酰基复合物的制备，立体化学和传真动力学，N'-二氧化氮或其3,3'-二甲基衍生物
8. Reactions at the Rhodium Vertex of a Rhodacarborane Cluster. Preparation, Crystal and Solution Structure, and Reactions of 3,3-(Ph3P)2-3(HSO)4-3,1,2-RhC2B9H11.O(C2H5)2. [R] . Kalb, W. C., Teller, R. G., Hawthorne, M. F. 1979

机译：Rhodacarborane簇的铑顶点的反应。 3,3-（ph3p）2-3（HsO）4-3,1,2-RhC2B9H11.O（C2H5）2的制备，晶体和溶液结构以及反应。

A novel preparation of 3,3-dimethylbutyraldehyde via isomerization of 3,3-dimethyl-1-butene epoxide

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