Grain-boundary cation diffusion in ceria tetragonal zirconia determined by constant-strain-rate deformation tests

摘要

Ceria tetragonal zirconia polycrystals with a content of 12mol% ceria (CeTZP) have been tested in compression at constant strain rate between 1150 °C and 1300 °C. An accurate analysis of the stress-strain curves has permitted to determine the value of the grain boundary cation diffusion. The results are compared with those reported in literature for this alloy and yttria tetragonal zirconia polycrystals (YTZP). An isotopic effect is found to correlate both grain boundary diffusion coefficients.