Synthesis of La_(0.9)Sr_(0.1)Ga_(0.8)Mg_(0.2)O_(2.85) powder by gel combustion route with two-step doping strategy

摘要

A two-step doping strategy was applied to the synthesis of La_(0.9)Sr_(0.1)Ga_(0.8)Mg_(0.2)O_(2.85) (LSGM1020) powder by a gel combustion method. The Mg-doped LaGaO_3 powder was prepared in the first step, and Sr incorporation in the Mg-doped LaGaO_3 powder was done in the second step to obtain the final LSGM1020 powder. The two-step procedure is effective in preparing higher purity powders than the traditional one-step procedure. Rietveld refinement of X-ray powder diffraction (XRD) patterns shows that incorporation of Mg in LaGaO_3 in the first step enlarges the LaGaO_3 lattice: this facilitates the incorporation of Sr in the second doping step and thus high purity powder is obtained. Relatively phase pure LSGM1020 powder with only 3.1% of LaSrGaO_ was obtained after calcination at 1300 °C for 5h. Therefore, the two-step doping strategy is an effective procedure for the preparation of LSGM powders with high Sr- and Mg-doping levels.