High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp* Mo-V trinuclear cation by chemical reduction of Cp*2Mo2O5

Demirhan F.; Gun J.; Lev O.; Modestov A.; Poli R.; Richard P.

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High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp* Mo-V trinuclear cation by chemical reduction of Cp*2Mo2O5

机译：高氧化态水性有机金属化合物。通过化学还原Cp * 2Mo2O5形成以氧为中心的Cp * Mo-V三核阳离子的结构

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Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH-H2O yields a salt which is composed of [Cp*3Mo3O4 (O2CCF3)(3)](+) and [Zn-2(O2CCF3)(6)](2-) ions after crystallisation from THF-Et2O. [References: 26]

机译：在MeOH-H2O中通过锌/ CF3CO2H还原Cp * 2Mo2O5产生的盐由[Cp * 3Mo3O4（O2CCF3）（3）]（+）和[Zn-2（O2CCF3）（6）]（2-）组成THF-Et2O结晶后的离子。 [参考：26]

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《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |2002年第10期|共3页
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Demirhan F.; Gun J.; Lev O.; Modestov A.; Poli R.; Richard P.;
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1. High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp* Mo-V trinuclear cation by chemical reduction of Cp*2Mo2O5 [J] . Demirhan F., Gun J., Lev O., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2002,第10期

机译：高氧化态水性有机金属化合物。通过化学还原Cp * 2Mo2O5形成以氧为中心的Cp * Mo-V三核阳离子的结构
2. Reductive Cleavage of the N-N Bond of Hydrazine Induced by a Cationic Trinuclear Ruthenium Hexahydride Complex,[(Cp'Ru)_3(mu-H)_6]X (Cp' =eta~5-C_5Me_5;X = 1/2 SO_4,BF_4,PF_6,BPh_4) and Dihydrogen [J] . Yumiko Nakajima, Akiko Inagaki, Hiroharu Suzuki Organometallics . 2004,第17期

机译：阳离子三核六氢化钌络合物[（Cp'Ru）_3（mu-H）_6] X（Cp'= eta〜5-C_5Me_5; X = 1/2 SO_4，BF_4诱导的肼的NN键的还原裂解，PF_6，BPh_4）和二氢
3. Chemical Structures of Streptococcus pneumoniae Capsular Polysaccharide Type 39 (CPS39), CPS47F, and CPS34 Characterized by Nuclear Magnetic Resonance Spectroscopy and Their Relation to CPS10A [J] . C. Allen Bush, Jinghua Yang, Bingwu Yu, Journal of bacteriology . 2014,第18期

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4. Effect of Aldehyde Structure in the Cp2TiCl-Catalyzed Styrene Living Radical Polymerization Initiated by Carbonyl SET Reduction [C] . Alexandru D. Asandei, Yanhui Chen PMSE Symposia . 2006

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5. Chemical implications of the two-electron redox chemistry observed for Fe(3)(CO)(9)(mu(3)-PMn(CO)(2)Cp)(2): Reductive coupling in multielectron chemical transformations. [D] . Marzec, Alexander Joseph. 1998

机译：Fe（3）（CO）（9）（mu（3）-PMn（CO）（2）Cp）（2）的双电子氧化还原化学的化学意义：多电子化学转化中的还原偶联。
6. Chemical Structures of Streptococcus pneumoniae Capsular Polysaccharide Type 39 (CPS39) CPS47F and CPS34 Characterized by Nuclear Magnetic Resonance Spectroscopy and Their Relation to CPS10A [O] . C. Allen Bush, Jinghua Yang, Bingwu Yu, 2014

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7. Investigation into the reactivity of the metal-metal triple bond in Cp'(CO)2M2 (Cp' = .eta.5-C5Me5', M = Mo, W) vs. elemental sulfur. Formation of different Cp'2M2S4 isomers and crystal structures of Cp'2Mo2(.mu.-S2)(.mu.-S)2 and Cp'2(CO)2W2(.mu.-S)2S [O] . Brunner Henri, Meier W., Wachter Joachim, 1982

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8. Automated Feasibility Analysis of Cathodice Protection (CP) and ElectrochemicalChloride Extraction for Reinforced Concrete Bridge Structures in Pennsylvania [R] . Pamukcu, S., Yalcin, M. G., Burleigh, T. D., 2001

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High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp* Mo-V trinuclear cation by chemical reduction of Cp*2Mo2O5

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