首页> 外文期刊>Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry >Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru- and Os-polypyridine termini
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Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru- and Os-polypyridine termini

机译:通过Ru-和Os-聚吡啶末端之间的光致能量转移探测的聚氧乙烯链的折叠

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摘要

The exten of photoinduced energy-transfer between [Ru(bipy)_3]~(2+) and [Os(bipy)_3]~(2+) units attached to either end of a deca(oxoethylene) 33-atom chain can be used to show how the distribution of end-to-end distances in the ensemble of conformations changes in different solvents.
机译:连接在十(氧乙烯)33原子链任一端的[Ru(bipy)_3]〜(2+)和[Os(bipy)_3]〜(2+)单元之间的光诱导能量转移范围可以是用于显示构象集合中端对端距离的分布在不同溶剂中如何变化。

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