Synthesis, structural characterization and catalytic properties of a novel monomeric rhenium(v)methyl(oxo)bis(#eta#~2-picolinato) complex: [CH_3Re(O)(pic)_2]

摘要

A methyl mono-oxo rhenium(v) complex with two picolinato chelating ligands has been synthesized and structurally characterized. When reacted with excess 10 or 30% H_2O_2 it forms peroxo species responsible for the catalytic activity of a highly selective two-phase medium.