Crystal structure and ferromagnetic behaviour of a novel tetranuclear copper(II) complex with an open cubane-like Cu_4O_4 framework

Xiang Shi Tan; Yuki Fujii; Ryoji Nukada; Masahiro Mikuriya; Yoshiharu Nakano

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Crystal structure and ferromagnetic behaviour of a novel tetranuclear copper(II) complex with an open cubane-like Cu_4O_4 framework

机译：具有类似古巴的开放式Cu_4O_4骨架的新型四核铜（II）配合物的晶体结构和铁磁行为

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The novel tetranuclear copper(II) complex [Cu_4(hpda)_4]-[ClO_4]_4 centre dot H_2O (Hhpda = N-(2-hydroxyethyl)-1,3-propane-diamine) with an open cubane-like Cu_4O_4 framework has been obtained and characterized by X-ray crystallography and magnetic measurements, exhibiting strongly ferromagnetic exchange interaction.

机译：新型四核铜（II）配合物[Cu_4（hpda）_4]-[ClO_4] _4中心点H_2O（Hhpda = N-（2-羟乙基）-1,3-丙烷-二胺），具有开放的类似古巴的Cu_4O_4骨架已通过X射线晶体学和磁性测量获得并表征了这些元素，表现出强铁磁交换相互作用。

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《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |1999年第15期|共2页
作者
Xiang Shi Tan; Yuki Fujii; Ryoji Nukada; Masahiro Mikuriya; Yoshiharu Nakano;
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1. Crystal structure and ferromagnetic behaviour of a novel tetranuclear copper(II) complex with an open cubane-like Cu_4O_4 framework [J] . Xiang Shi Tan, Yuki Fujii, Ryoji Nukada, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1999,第15期

机译：具有类似古巴的开放式Cu_4O_4骨架的新型四核铜（II）配合物的晶体结构和铁磁行为
2. Chiral tetranuclear mu(3)-alkoxo-bridged Copper(II) complex with 2+4 cubane-like Cu4O4 core framework and ferromagnetic ground state [J] . Burkhardt A, Spielberg ET, Gorls H, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第7期

机译：手性四核mu（3）-烷氧基桥接的铜（II）配合物，具有2 + 4古巴样Cu4O4核心骨架和铁磁基态
3. A μ _3-alkoxo-bridged tetranuclear [Cu _4L _2] copper(II) complex of a hexadentate N_2O_4 donor ligand with a [6 + 0] Cu_4O_4 cubane core: Synthesis, crystal structure, and magnetic properties [J] . Maity D., Jana A.D., Debnath M., European journal of inorganic chemistry . 2010,第22期

机译：μ_3-烷氧基桥联的六齿N_2O_4供体配体与[6 + 0] Cu_4O_4古巴核心的四核[Cu _4L _2]铜（II）配合物：合成，晶体结构和磁性
4. Synthesis, crystal structure and properties of a metal-organic framework of tetraazamacrocycle copper(II) complex with benzenetetracarboxylic acid [C] . Shingo Mizutani, Hiroshi Ohki, Atsushi Ishikawa 日本化学会春季年会講演予稿集 . 2018

机译：用苯甲酸四胱铜（II）络合物的金属 - 有机骨架的合成，晶体结构和性能
5. I. THE SYNTHESES, SOLUTION BEHAVIOR, CRYSTAL STRUCTURES AND MAGNETIC PROPERTIES OF SOME IMIDAZOLATE BRIDGED COPPER(II) COMPLEXES. II. THE CRYSTAL STRUCTURE AND MAGNETIC PROPERTIES OF A TRICOPPER(II) CLUSTER CONTAINING A TRIPLY BRIDGING CARBONATE GROUP. [D] . KOLKS, GARY ARNOLD. 1980

机译：I.某些咪唑基桥接铜（II）配合物的合成，溶液行为，晶体结构和磁性。二。含碳桥基的三铜（II）簇的晶体结构和磁性。
6. Crystal structure of a tetranuclear CuII complex with an ONN′-donor Schiff base ligand: hexa-μ2-acetato-bis(2-{(2266-tetramethylpiperidin-4-yl)iminomethyl}phenolato-κ3ONN′)tetracopper(II) [O] . Guohui Huang, Xiaoxuan Liu 2016

机译：具有ONN-施主希夫碱配体的四核CuII配合物的晶体结构：六-μ2-乙酰基-双（2-{（（2266-四甲基哌啶-4-基）亚氨基甲基}酚基-κ3ONN）四铜（II）
7. Crystal structure of a tetranuclear CuII complex with an O,N,N′-donor Schiff base ligand: hexa-μ2-acetato-bis(2-{[(2,2,6,6-tetramethylpiperidin-4-yl)imino]methyl}phenolato-κ3O,N,N′)tetracopper(II) [O] . Guohui Huang, Xiaoxuan Liu 2016

机译：具有O，N，N'-供体席夫碱配体的四核CuII配合物的晶体结构：六-μ2-乙酸根 - 双（2 - {[（2,2,6,6-四甲基哌啶-4-基）亚氨基]甲基}苯酚-κ3O，N，N'）tetracopper（II）
8. CRYSTAL STRUCTURES OF NICKEL AND COPPER COMPOUNDS PART I. TWO BIS COMPLEXES OF 2.2’-IMINOBIS (ACETAMIDOXIME) PART II REGULAR OCTAHEDRAL COPPER (II) COMPLEXES [R] . DAVID LAWRENCE CULLEN 1969

机译：镍和铜化合物的晶体结构第一部分2.2'-亚氨基（乙酰氨基）第二部分正二甲基铜（Ⅱ）配合物的两个双配合物

Crystal structure and ferromagnetic behaviour of a novel tetranuclear copper(II) complex with an open cubane-like Cu_4O_4 framework

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