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首页> 外文期刊>Journal of Rheology >Simple shear and small amplitude oscillatory rectilinear shear permeation flows of cholesteric liquid crystals
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Simple shear and small amplitude oscillatory rectilinear shear permeation flows of cholesteric liquid crystals

机译:胆甾型液晶的简单剪切和小振幅振荡直线剪切渗透流

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A model of rod-like cholesteric liquid crystals subjected to slow steady simple shear and low frequency small amplitude oscillatory shear flow is formulated and applied to permeation flow, also known as Helfrich permeation flow [Helfrich (1969, 1970)], when the cholesteric helix is oriented along the velocity direction and the orientation distortions retain the original planar chiral structure. In permeation flow the elastic forces exactly balance viscous forces. The presence of a small internal length scale (pitch of the helix leads to boundary layer behavior in the velocity and orientation fields at any shear rate and at any driving frequency. The thickness of the boundary layer region is of the order of the pitch. The apparent viscosity is larger than typical nematic viscosities by a factor proportional to the ratio of the gap thickness to the pitch length. The effect is due to the Ericksen elastic stress. The response of cholesterics to small amplitude oscillatory shear corresponds to a purely viscous material. The out-of-phase stress component vanishes because the viscous force is exactly cancelled by the elastic force. In the terminal region, the loss modulus G" exhibits a classical frequency ω dependence (G" ∝ ω) but its magnitude is much greater than for other cholesteric flows by a factor proportional to the ratio of the gap thickness to the pitch length.
机译:建立了棒状胆甾型液晶模型,该模型经历了缓慢稳定的简单剪切和低频小振幅振荡剪切流,并将其应用于渗透流,也称为Helfrich渗透流[Helfrich(1969,1970)],当胆甾醇螺旋发生时沿速度方向取向,并且取向畸变保留了原始的平面手性结构。在渗透流中,弹性力恰好平衡了粘性力。内部长度尺度的存在(螺旋的螺距导致在任何剪切速率和任何驱动频率下在速度和取向场中的边界层行为。边界层区域的厚度约为螺距的量级。表观粘度比典型向列型粘度大一个与间隙厚度与节距长度之比成比例的因子,其影响归因于埃里克森弹性应力,胆甾醇对小振幅振荡剪切的响应相当于一种纯粘性材料。由于粘性力被弹力完全抵消了,因此异相应力分量消失了。在末端区域,损耗模量G“表现出经典的频率ω依赖性(G” ∝ω),但其幅值远大于对于其他胆甾型流动,其系数与间隙厚度与节距长度之比成正比。

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