FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)(3)(H2O)Cl] x [Ru(NO)(NH3)(3)(OH)Cl][Ru(NO)(NH3)Cl-4](2)Cl center dot 2H(2)O

摘要

The structure of the interaction products of (NH4)(2)[Ru(NO)Cl-5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)(3)(H2O)Cl][Ru(NO)(NH3)(3)(OH)Cl] x [Ru(NO)(NH3)Cl-4](2)Cl center dot 2H(2)O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) angstrom, b = 8.202(2) angstrom, c = 11.844(2) angstrom; beta = 101.54(3)degrees.