Ionic strength effect on the Stability of the V(V) + IDA complex

摘要

In this research the interaction of dioxovanadium(V) with iminodiacetic acid has been considered at 25∈°C and pH=1.00-2.50 in an ionic strength range of 0.1 to 1.0 mol·dm~(-3) of NaClO_4 by UV spectrophotometric and potentiometric techniques. Only one species, VO _2H_2L~+, was assumed on the basis of two stoichiometric models. The extended Debye-Hückel theory predicts the first order effects in simple electrolyte solutions. Interactions between the reacting species and the ionic medium are taken into account in the specific ion interaction model. Parabolic, specific ion interaction, and extended Debye-Hückel models have been compared and it has been shown that the parabolic model with two coefficients is satisfactory for this complexation reaction. The results have also been compared with the literature values.