Optimization of Nb-substitution and Cs~+/Sr~(+2) ion exchange in crystalline silicotitanates (CST)

摘要

Crystalline silicotitanate inorganic ion exchanger, with a sitinakite structure is a candidate material for remediation of aqueous nuclear waste streams. Niobium substituted crystalline silicotitanates (Nb-CST) with varying concentrations of Nb (2, 4, 8, 12 and 24 mmol) and with constant concentrations of Ti-12 mmol, Si-16 mmol, Na-165 mmol were prepared hydrothermally and the products were characterized using techniques viz., XRD, SEM/EDS, DTA/TGA, surface area respectively. Batch experiments were carried out to study the kinetics of uptake of Cs~(137) and Sr~(90), to estimate the decontamination factor (DF) values and distribution coefficients (K_d) for the above synthesized Nb-CST samples from actual radioactive waste solutions. The DF values for uptake of Cs and Sr by N_b-CST for the optimized Nb-concentration of 4 mmol after 24 h of equilibration was 355 and 136 respectively. The Kd values for uptake of Cs and Sr for Nb-CST (Nb-4 mmol) after 24 h of equilibration was found to be 35,490 and 13,500 ml/g respectively. The ion exchange capacity of Nb-CST (Nb-4 mmol) towards Sr ~(90) and Cs~(137) was estimated to be 11.8 and 3.2 meq/g respectively.