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Recycling Oily Sludge Pyrolysis Residues as Nano-adsorbents

机译:回收含油污泥热解残渣作为纳米吸附剂

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Oily sludge is a major oily waste originating from the oil refining industry production process. It is very difficult to handle and may harm portions (i.e., ecosys- tems and human health) of the environment. Oil and gas may be separated from oily sludge and economically recovered by pyrolysis technology. However, the by-product residue of pyrolysis would likely contribute to secondary pollution if a disposal method was not competent. A novel nano-adsorbent, NMA-12, was developed by synthesization between a supermolecule compound and an oily sludge pyrolysis residue with participation from chemically modified nanometer materials. Static adsorption and desorption kinetic characteristics of the adsorbent (NMA-12) were studied with Congo Red as the test adsorbate. Results suggest adsorption equilibrium time was approximately 150 minutes and that the apparent adsorption rate constant of Congo Red was k_(298) = 0.02 s~(-1). Desorption volume of Congo Red at the same time was greater in stripping liquid where it reached 80.7% versus in pure water. This research was devoted to finding a feasible technology for treatment of oily sludge pyrolysis residues as a means of resource recycling.
机译:含油污泥是来自炼油行业生产过程的主要含油废物。这非常难以处理,并且可能损害环境的某些部分(即生态系统和人体健康)。石油和天然气可以与油性污泥分离,并通过热解技术经济地回收。但是,如果处置方法不可行,热解的副产物残留可能会造成二次污染。通过在化学修饰的纳米材料的参与下,在超分子化合物和油性污泥热解残渣之间合成,开发了一种新型的纳米吸附剂NMA-12。以刚果红为测试被吸附物研究了吸附剂(NMA-12)的静态吸附和解吸动力学特性。结果表明,吸附平衡时间约为150分钟,刚果红的表观吸附速率常数为k_(298)= 0.02 s〜(-1)。在汽提液中,刚果红的解吸体积要比纯水中的大,达到80.7%。这项研究致力于寻找一种可行的技术来处理含油污泥的热解残留物,作为资源循环利用的手段。

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