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Effect of maleic anhydride grafted polyethylene on the properties of chopped carbon fiber/wood plastic composites

机译:马来酸酐接枝聚乙烯对短切碳纤维/木塑复合材料性能的影响

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摘要

Chopped carbon fibers reinforced wood plastic composites were fabricated using a two-step extrusion process. As a coupling agent, maleic anhydride polyethylene was added for improving the interfacial adhesion between the chopped carbon fibers and plastic matrix. The results showed that the mechanical properties of the maleic anhydride polyethylene-added composites were significantly improved compared to that without maleic anhydride-grafted polyethylene. Tensile strength, flexure strength and impact strength were increased by 97%-133%, 113%-119% and 181%-251%, respectively, which were very close to the strengths of structural timber. The adding of maleic anhydride polyethylene also influenced the electrical property of chopped carbon fibers reinforced wood plastic composites. The volume electrical resistivity of the composites with maleic anhydride polyethylene was higher. The scanning electron microscopy was used to examine the morphology of brittle fracture cross-section paralleled to the extrusion direction. It was observed that the interfacial adhesion was improved with the incorporation of maleic anhydride polyethylene. Chopped carbon fibers were coated by high-density polyethylene and the bonding connections were formed on the fiber surfaces. The distribution direction of chopped carbon fibers was parallel to the extrusion direction and dispersed more uniformly in the maleic anhydride polyethylene-added composites.
机译:切碎的碳纤维增强木塑复合材料使用两步挤压工艺制造。作为偶联剂,添加马来酸酐聚乙烯以改善短切碳纤维与塑料基质之间的界面粘合性。结果表明,与不添加马来酸酐接枝聚乙烯的复合材料相比,添加马来酸酐聚乙烯的复合材料的机械性能得到了显着改善。拉伸强度,弯曲强度和冲击强度分别提高了97%-133%,113%-119%和181%-251%,非常接近结构木材的强度。马来酸酐聚乙烯的添加也影响短切碳纤维增强木塑复合材料的电性能。具有马来酸酐聚乙烯的复合材料的体积电阻率较高。扫描电子显微镜用于检查平行于挤出方向的脆性断裂横截面的形态。观察到,通过引入马来酸酐聚乙烯,界面粘合性得到改善。短切的碳纤维被高密度聚乙烯覆盖,并且在纤维表面上形成了粘结连接。短切碳纤维的分布方向与挤出方向平行,并在添加顺丁烯二酸酐聚乙烯的复合材料中更均匀地分散。

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