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Experimental investigations of clathrate hydrate inhibition in water based drilling fluid using green inhibitor

机译:绿色抑制剂抑制水基钻井液中包合物水合物的实验研究

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Formation of hydrate plugs in drilling fluid is a serious problem in oil and gas industries. Recently, interest in the development of green hydrate inhibitors increased which can be used as substitutes for available low dosage hydrate inhibitors (LDHIs). In this research paper the effect of porcine pancreatic lipase on the formation of tetrahydrofuran (THF) clathrate hydrate was studied by determining the time for nucleation of hydrate crystals (induction time). Pancreatic lipase inhibits the formation of clathrate hydrate and its growth by adsorbing to different hydrate crystal faces. The ability of pancreatic lipase to eliminate or extends the "memory effect" was also studied and compared with polyvinylpyrrolidone (PVP). Pancreatic lipase found to be a better inhibitor than PVP and also suppresses the "memory effect" more efficiently. The effect of pancreatic lipase on the rheology of drilling fluid was studied as rheological characteristics of drilling fluid are most crucial for safe drilling operations. It was found that drilling fluid performs satisfactorily in terms of rheology at different concentrations of pancreatic lipase. This research paper shows that pancreatic lipase can be effectively used in drilling fluid as a green hydrate inhibitor. (C) 2016 Elsevier B.V. All rights reserved.
机译:在石油和天然气工业中,钻井液中水合物塞的形成是一个严重的问题。近来,对绿色水合抑制剂的开发的兴趣增加了,其可以用作可用的低剂量水合抑制剂(LDHI)的替代品。通过确定水合物晶体成核的时间(诱导时间),研究了猪胰脂肪酶对四氢呋喃(THF)包合物水合物形成的影响。胰腺脂肪酶通过吸附到不同的水合物晶体表面来抑制笼形水合物的形成及其生长。还研究了胰腺脂肪酶消除或扩展“记忆效应”的能力,并将其与聚乙烯吡咯烷酮(PVP)进行了比较。发现胰脂肪酶是比PVP更好的抑制剂,并且还更有效地抑制“记忆效应”。研究了胰脂肪酶对钻井液流变性的影响,因为钻井液的流变特性对安全钻井作业至关重要。已经发现,在不同浓度的胰脂肪酶下,钻井液的流变性令人满意。该研究表明,胰腺脂肪酶可以作为绿色水合物抑制剂有效地用于钻井液中。 (C)2016 Elsevier B.V.保留所有权利。

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