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Effects of zinc borate and microcapsulated red phosphorus on mechanical properties and flame retardancy of polypropylene/magnesium hydroxide composites

机译:硼酸锌和微囊化红磷对聚丙烯/氢氧化镁复合材料力学性能和阻燃性的影响

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摘要

In this paper, the mechanical properties and flame retardancy of zinc borate (ZB) and microcapsulated red phosphorus (MRP) with modified magnesium hydroxide (MH) in flame-retardant polypropylene (PP) were studied by mechanical properties test, UL-94 test, and thermogravimetric analysis (TGA). The crystallization behaviors of the composites were investigated by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). The addition of ZB could improve tensile strength and elongation at break of PP/MH composite. The MRP powders had a little effect on the mechanical properties of the PP composites. DSC results showed the addition of ZB and MRP weakened the heterogeneous nucleation effect of MH on PP. The addition of ZB and MRP had a great effect on the flammability of the PP/MH/EG composites. The thermal stability of PP/MH/ZB and PP/MH/ZB/MRP composites was better than that of PP/MH composite.
机译:本文通过机械性能测试,UL-94测试,硼酸锌(ZB)和改性氢氧化镁(MH)在微囊化红磷(MRP)中对阻燃聚丙烯(PP)的力学性能和阻燃性进行了研究,和热重分析(TGA)。通过差示扫描量热法(DSC)和偏振光学显微镜(POM)研究了复合材料的结晶行为。 ZB的添加可以提高PP / MH复合材料的拉伸强度和断裂伸长率。 MRP粉末对PP复合材料的机械性能影响很小。 DSC结果表明,ZB和MRP的加入削弱了MH对PP的异质成核作用。 ZB和MRP的添加对PP / MH / EG复合材料的可燃性有很大影响。 PP / MH / ZB和PP / MH / ZB / MRP复合材料的热稳定性优于PP / MH复合材料。

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