Behavior of protonated cydopropyl intermediates during polyalphaolefin synthesis: Mechanism and predicted product distribution

摘要

A new mechanism for the origin of multiple skeletal isomers observed in the cationic dimerization of 1-decene is proposed, and products that should form based on this mechanism are predicted. A protonated cydopropyl intermediate appeared to form directly from combination of 2-decyl carbocation with 1-decene,. formation of this intermediate did not appear to occur via ring closure of a branched secondary carbocation. The authors propose that rapid, repeated isomerizations of the protonated cyclopropyl intermediates lead to multiple skeletal isomers in decene dimers. The proposed mechanism can account for structures previously identified in mixtures of decene dimers and butene dimers.