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首页> 外文期刊>Journal of Physics. Condensed Matter >Non-metallic transport in molecular solids versus dimensionality
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Non-metallic transport in molecular solids versus dimensionality

机译:分子固体中的非金属传递与尺寸

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Path integral techniques and the Green's function formalism are applied to study the time- and temperature-dependent scattering of a polaronic quasiparticle using a local anharmonic potential in a bath of diatomic molecules. The electrical resistivity has been computed for any molecular lattice dimensionality for different values of the electron-phonon coupling and intermolecular forces. A broad resistivity peak with non-metallic behaviour at temperatures larger than similar or equal to 100 K is predicted by the model for sufficiently strong polaron-local potential coupling strengths. This peculiar behaviour, ascribed to purely structural effects, is favoured for low dimensionality. [References: 35]
机译:应用路径积分技术和格林函数形式论,利用双原子分子浴中的局部非谐势来研究极化子准粒子的时间和温度相关散射。对于电子-声子耦合和分子间力的不同值,已经针对任何分子晶格尺寸计算了电阻率。对于足够强的极化子-局部电势耦合模型,该模型预测了在大于或等于100 K的温度下具有非金属行为的宽电阻率峰。归因于纯粹的结构效应,这种特殊的行为对于低尺寸是有利的。 [参考:35]

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