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Microstructural evolution of nuclear grade graphite induced by ion irradiation at high temperature environment

机译:高温环境下离子辐照诱导核级石墨的组织演变

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This study simulates the Wigner Effect of nuclear-grade graphite in a High Temperature Gas-cooled Reactor (HTGR). The graphite was artificially irradiated with 3 MeV C~(2+) ions to mimic the fast neutron-radiation damage of the HTGR core environment. The irradiation temperatures were controlled between the range of 500-800 °C in a high vacuum environment of 10~(-7) torr. This high-dosage radiation creates enormous amounts of Frenkel pairs, which induce lattice swelling. These Frenkel vacancies and interstitials generate new strain fields and, hence, store energy in the distorted crystalline structure. The structural integrity of nuclear grade graphite was quantified using high-resolution transmission electron microscopy (HRTEM). The microstructure was estimated by the fast Fourier transform of HRTEM images. Within the samples irradiated with 10 dpa at 600 °C, the d-spacing of {0 0 0 2} expanded from 0.336 nm to 0.396 nm accompanying with the greatest distorted graphite microstructure. The c-axis of graphite swelled approximately 18% and the disorder coefficient was 1.10 ± 0.17 (1m). The synchrotron X-ray experimental results, gauged from 500 μm~3 volume, suggesting that the ion-implanted graphite only deformed locally and epitaxially. This study also presents possible mechanisms.
机译:这项研究模拟了高温气冷堆(HTGR)中核级石墨的威格纳效应。用3 MeV C〜(2+)离子人工照射石墨,以模拟HTGR核心环境对中子的快速辐射破坏。在10〜(-7)to的高真空环境下,将辐照温度控制在500-800°C之间。这种高剂量辐射会产生大量的弗伦克尔对,从而引起晶格膨胀。这些Frenkel空位和间隙产生了新的应变场,因此将能量存储在变形的晶体结构中。核级石墨的结构完整性使用高分辨率透射电子显微镜(HRTEM)进行定量。通过HRTEM图像的快速傅里叶变换来估计微观结构。在600℃下用10 dpa辐照的样品中,{0 0 0 2}的d间距从0.336 nm扩展到0.396 nm,同时石墨晶体结构最大。石墨的c轴膨胀约18%,无序系数为1.10±0.17(1 / nm)。从500μm〜3体积测量的同步加速器X射线实验结果表明,离子注入的石墨仅局部变形且外延变形。这项研究还提出了可能的机制。

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